88-26-6Relevant articles and documents
Synthetic method of antioxidant
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Paragraph 0014; 0032; 0035; 0039; 0042; 0046; 0049; ..., (2021/06/23)
The invention discloses a synthesis method of an antioxidant, which comprises the following steps: reacting cyanuric chloride with an intermediate 8 and an intermediate 11 in sequence through temperature control to prepare an intermediate 12, hydrolyzing the intermediate 12, grafting a product on nano silicon dioxide to prepare the antioxidant; wherein the antioxidant is grafted with the nano silicon dioxide, so that the antioxidant can be fully dispersed when being mixed with a polymer, does not migrate along with the increase of service time, contains hindered phenol and phosphite structures, can provide hydrogen atoms to prevent the formation of chain free radicals, and reacts with the chain free radicals to achieve the purpose of inhibiting oxidation. Meanwhile, unstable hydrogen peroxide can be decomposed into stable compounds, so that formation of new free radicals is prevented, and the purpose of terminating a chain reaction is achieved.
Unusual transformation of 4-hydroxy/methoxybenzylic alcohols via C[sbnd]C ipso-substitution reaction using proton-exchanged montmorillonite as media
Chen, Dongyin,Chen, Xuan,Dong, Zezhong,Jiang, Nan,Li, Fei,Yun, Yangfang,Zhou, Yu
supporting information, (2020/11/12)
We present here proton-exchanged montmorillonite-mediated an unusual transformation of 4-hydroxy and 4-methoxybenzylic alcohols to form symmetrical benzylic ethers and diarylmethanes under mild conditions. Nuclear magnetic resonance spectroscopy and density functional theory calculations support a plausible mechanism, which includes a distinctive aromatic C[sbnd]C ipso-substitution reaction with a hydroxymethyl group as the C-based leaving group.
Synthetic method of 4-hydroxymethyl-2, 6-di-tert-butylphenol
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Paragraph 0007; 0008; 0009, (2018/10/26)
The invention provides a synthetic method of 4-hydroxymethyl-2, 6-di-tert-butylphenol. The synthetic method includes the steps of adopting the 2, 6-di-tert-butylphenol and paraformaldehyde or formaldehyde aqueous solution as starting material, adding solvent and catalysts, performing one-step reaction in a hydrothermal synthesis reactor and under a certain reaction temperature for a certain reaction time and then generating a target product. The synthetic method of 4-hydroxymethyl-2, 6-di-tert-butylphenol has the advantages of simple steps, convenient operation, green reaction process, and higher synthesis efficiency than an existing synthesis method.