174912-77-7Relevant academic research and scientific papers
Unlikeliness of Pd-free gold(I)-catalyzed sonogashira coupling reactions
Lauterbach, Thorsten,Livendahl, Madeleine,Rosellon, Antonio,Espinet, Pablo,Echavarren, Antonio M.
, p. 3006 - 3009 (2010)
The Sonogashira coupling reaction is not catalyzed by AuI/dppe in the absence of Pd complexes. However, addition of 0.1 mol % of Pd(0) led to efficient cross-coupling reactions. The most plausible catalytic cycles for the Au-catalyzed cross-coupling reactions have been examined and are unlikely in the absence of Pd contamination.
