175025-14-6Relevant articles and documents
Synthesis of (1R, 1R')-2,6-bis[1-(diphenylphosphino)ethyl]pyridine and its application in asymmetric transfer hydrogenation
Jiang,Van Plew,Murtuza,Zhang
, p. 797 - 800 (1996)
A C2 symmetric tridentate ligand, (1R, 1R') 2,6-Bis[1-(diphenylphosphino)ethyl]pyridine, has been synthesized in enantiomerically pure form. A practical method to synthesize a variety of chiral pyridyl diols is reported. Asymmetric transfer hydrogenation is achieved using the tridentate ligand.
Stereocomplexity and stereoselective synthesis of triamine molecules bearing four chiral carbon centers: Stereodifferentiated preparation of all 10 stereoisomers of 2,6-bis[1-(1-phenylethylamino)ethyl]pyridines
Uenishi, Jun'ichi,Aburatani, Sachiko,Takami, Taro
, p. 132 - 138 (2007/10/03)
Compounds (S,S)-2,6-bis(1-hydroxyethyl)pyridine, (R,R)-2,6-bis(1- acetoxyethyl)pyridine, and (1R,1′S)-2-(1-acetoxyethyl)-6-(1′- hydroxyethyl)pyridine were obtained by lipase-catalyzed kinetic acetylation of 2,6-bis(1-hydroxyethyl)pyridine as enantiomerica