175025-41-9Relevant academic research and scientific papers
Cycloaromatization of enediyne model compounds via a reaction cascade triggered by hydrolysis of the α-alkynylmalonates
Shibuya, Masayuki,Wakayama, Masakazu,Naoe, Yoshimitsu,Kawakami, Tadaaki,Ishigaki, Katsuya,Nemoto, Hisao,Shimizu, Hisashi,Nagao, Yoshimitsu
, p. 865 - 868 (2007/10/03)
Diethyl α-methoxy-α-alkynylmalotate derivatives of cis-enediynes were synthesized and they produced toluenebiradicals via the reaction cascade triggered by ester hydrolysis. Deuterium labeling studies suggested that the reaction involved the self quenchin
