17531-22-5Relevant academic research and scientific papers
Stereoselective synthesis of (E)-chloroenynes or (E,E)-chlorodienes starting from a stereoisomeric mixture of 1,2-dichloroethylenes
Alami, Mouad,Peyrat, Jean-Fran?ois,Brion, Jean-Daniel
, p. 3007 - 3009 (2007/10/03)
Under palladium or nickel catalysis, a stereomeric mixture 1:1 of (Z) and (E)-1,2-dichloroethylene readily reacts with 1-alkynes, vinyl alanes or vinyl boranes to afford selectively the corresponding (E)-coupling product in good to excellent isolated yiel
Palladium-catalysed Arylation of 1,3-Dienes: A Highly Chemo, Regio and Stereoselective Synthesis of (E,E) Conjugated Dienic Aromatics.
Jeffery, Tuyet
, p. 1989 - 1992 (2007/10/02)
(E,E) conjugated aromatic dienes can be efficiently prepared from aromatic halides and 1,3-dienes with high chemo, regio and stereoselectivities. Key words: Palladium; arylation; dienes; silver(I) salt; thallium(I) salt; (E,E) conjugated dienic aromatics.
