175439-05-1Relevant articles and documents
A new approach to the synthesis of 2-vinylthiophenes and selenophenes; competition between free radical and anionic cycloaromatization of bridged di- and tetrapropargylic sulfides and selenides
Zafrani, Yossi,Cherkinsky, Marina,Gottlieb, Hugo E.,Braverman, Samuel
, p. 2641 - 2649 (2007/10/03)
A series of unknown di- and tetrapropargylic sulfides and selenides have been prepared. In the presence of t-BuOK in dry THF these compounds underwent isomerization to the corresponding diallenes, followed by a tandem anionic cyclization and aromatization
A direct route to conjugated enediynes from dipropargylic sulfones by a modified one-flask Ramberg-Baecklund reaction
Cao, Xiaoping,Yang, Yuying,Wang, Xiaolong
, p. 2485 - 2489 (2007/10/03)
The reaction of dipropargylic sulfones with dibromodifluoromethane in the presence of alumina-supported KOH in dichloromethane solution results in facile rearrangement affording the corresponding conjugated linear and cyclic enediynes in good yields. This result shows that the direct transformation of a- and a′-hydrogen bearing sulfones assembles enediyne units without resorting to the prior preparation of the a-halo sulfone precursors in a separate step.
Direct conversion of dipropargylic sulfones into (E)- and (Z)-Hex-3-ene-1,5-diynes by a modified one-flask Ramberg-Backlund reaction
Cao,Chan,Chow
, p. 1049 - 1052 (2007/10/03)
(E)- and (Z)-enediynes 7 are readily synthesized in good yields from a one-pot modified Ramberg-Backlund reaction from dipropargylic sulfones 5.