175469-97-3Relevant academic research and scientific papers
STEREOCHEMICAL STUDY OF CYCLOADDITIONS USING ERYTHROSE AND THREOSE BASED DIENES AS SOURCE OF 2-NONULOSONIC ACID ANALOG
Lubineau, Andre,Arcostanzo, Helene,Queneau, Yves
, p. 1307 - 1328 (2007/10/03)
The stereochemical outcome of the hetero Diels Alder reaction of an erythrose based diene with sodium glyoxylate was rationalyzed by preparing the same compounds via decarboxylation of 2-carbethoxy-2-deoxy-2-ulosonic esters, obtained by cycloaddition with diethyl ketomalonate.Further chemical transformations of cycloadducts allowed us to prepare a series of new 2-nonulosonic acid derivatives.
