175551-72-1

Basic information

• Product Name: (3R,4R,5E)-6-((S,2E,4E)-8-(tert-butyldimethylsilyloxy)-6-(tert-butyldiphenylsilyloxy)-4-methylocta-2,4-dienylcarbamoyl)-2,4-dimethylhex-5-en-3-yl 2,2,2-trichloroethyl (2R)-pyrrolidine-1,2-dicarboxylate
• Synonyms: (3R,4R,5E)-6-((S,2E,4E)-8-(tert-butyldimethylsilyloxy)-6-(tert-butyldiphenylsilyloxy)-4-methylocta-2,4-dienylcarbamoyl)-2,4-dimethylhex-5-en-3-yl 2,2,2-trichloroethyl (2R)-pyrrolidine-1,2-dicarboxylate
• CAS NO: 175551-72-1
• Molecular Weight: 950.631
• Mol File: 175551-72-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (3R,4R,5E)-6-((S,2E,4E)-8-(tert-butyldimethylsilyloxy)-6-(tert-butyldiphenylsilyloxy)-4-methylocta-2,4-dienylcarbamoyl)-2,4-dimethylhex-5-en-3-yl 2,2,2-trichloroethyl (2R)-pyrrolidine-1,2-dicarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: (3R,4R,5E)-6-((S,2E,4E)-8-(tert-butyldimethylsilyloxy)-6-(tert-butyldiphenylsilyloxy)-4-methylocta-2,4-dienylcarbamoyl)-2,4-dimethylhex-5-en-3-yl 2,2,2-trichloroethyl (2R)-pyrrolidine-1,2-dicarboxylate(175551-72-1)
• EPA Substance Registry System: (3R,4R,5E)-6-((S,2E,4E)-8-(tert-butyldimethylsilyloxy)-6-(tert-butyldiphenylsilyloxy)-4-methylocta-2,4-dienylcarbamoyl)-2,4-dimethylhex-5-en-3-yl 2,2,2-trichloroethyl (2R)-pyrrolidine-1,2-dicarboxylate(175551-72-1)

Safety Data

• Hazardous Substances Data: 175551-72-1(Hazardous Substances Data)

Upstream product

• 175551-70-9 (S,2E,4E)-8-(tert-butyldimethylsilyloxy)-6-(tert-butyldiphenylsilyloxy)-4-methylocta-2,4-dienenitrile 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 40466-98-6 2,4-dimethylpent-2-en-1-ol 
• 96429-43-5 (E)-6-((tert-butyldimethylsilyl)oxy)hex-3-en-2-one 
• 82290-72-0 ethyl (E,4R,5R)-5-hydroxy-4,6-dimethylhept-2-enoate 
• 89922-82-7 3-(tert-butyldimethylsilanyloxy)propionaldehyde 
• 73842-99-6 3-tert-butyldimethylsilyloxy-1-propanol 
• 67513-37-5 (2E,4E)-ethyl 4,6-dimethylhepta-2,4-dienoate 
• 30567-25-0 2,4-dimethyl-pent-2-enal 
• 57691-99-3 (E)-2,4-dimethylpent-2-enal 
• 947417-19-8 (3R,4S)-6-(tert-butyldimethylsilanyloxy)-3,4-dihydroxyhexan-2-one 
• 947417-21-2 (4R,5S)-4-acetyl-5-(2-(tert-butyldimethylsilyloxy)ethyl)-1,3-dioxolan-2-one 
• 947417-33-6 (E,3R,4R)-6-(ethoxycarbonyl)-2,4-dimethylhex-5-en-3-yl 1-(2,2,2-trichloroethyl) (2R)-pyrrolidine-1,2-dicarboxylate 

Downstream Products

• 175551-76-5 (12E,17E,19E)-(7R,10R,11R,21S)-21-(tert-Butyl-diphenyl-silanyloxy)-10-isopropyl-11,19-dimethyl-9,26-dioxa-3,15,28-triaza-tricyclo[23.2.1.0^3,7]octacosa-1⁽²⁷⁾,12,17,19,25⁽²⁸⁾-pentaene-2,8,14,23-tetraone 
• 175551-73-2 (R)-Pyrrolidine-1,2-dicarboxylic acid 2-{(E)-(1R,2R)-4-[(2E,4E)-(S)-6-(tert-butyl-diphenyl-silanyloxy)-4-methyl-8-oxo-octa-2,4-dienylcarbamoyl]-1-isopropyl-2-methyl-but-3-enyl} ester 1-(2,2,2-trichloro-ethyl) ester 
• 21102-49-8 virginiamycin M2 
• 175551-79-8 (R)-Pyrrolidine-1,2-dicarboxylic acid 2-{(E)-(1R,2R)-4-[(2E,4E)-(S)-6-(tert-butyl-diphenyl-silanyloxy)-8-hydroxy-4-methyl-octa-2,4-dienylcarbamoyl]-1-isopropyl-2-methyl-but-3-enyl} ester 1-(2,2,2-trichloro-ethyl) ester 

Relevant articles and documents

De novo formal synthesis of (-)-virginiamycin M2 via the asymmetric hydration of dienoates

A de novo approach to the formal total synthesis of the macrolide natural product (-)-virginiamycin M2 has been achieved via a convergent approach. The absolute and relative stereochemistry of the nonpeptide portion of (-)-virginiamycin M2