175673-34-4Relevant academic research and scientific papers
A stereocontrolled enantiospecific route to tirandamycin B
Shiratani, Tomonori,Kimura, Kiyoshi,Yoshihara, Kousei,Hatakeyama, Susumi,Irie, Hiroshi,Miyashita, Masaaki
, p. 21 - 22 (1996)
The enal 15 was synthesized in enantiomerically pure form starting from (S)-3-benzyloxy-2-methylpropanol 3 via highly regio- and stereo-selective methylation of the γ,δ-epoxy acrylate 5 with trimethylaluminium in the presence of water, developing an enantiospecific route to tirandamycin B.
