A stereocontrolled enantiospecific route to tirandamycin B

DOI: 10.1039/cc9960000021

Source and publish data:

Chemical Communications p. 21 - 22 (1996)

Update date:2022-08-02

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Authors:

Shiratani, Tomonori

Kimura, Kiyoshi

Yoshihara, Kousei

Hatakeyama, Susumi

Irie, Hiroshi

Miyashita, Masaaki

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Article abstract of DOI:10.1039/cc9960000021

The enal 15 was synthesized in enantiomerically pure form starting from (S)-3-benzyloxy-2-methylpropanol 3 via highly regio- and stereo-selective methylation of the γ,δ-epoxy acrylate 5 with trimethylaluminium in the presence of water, developing an enantiospecific route to tirandamycin B.

Full text of DOI:10.1039/cc9960000021

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