Chemical Communications p. 21 - 22 (1996)
Update date:2022-08-02
Topics:
Shiratani, Tomonori
Kimura, Kiyoshi
Yoshihara, Kousei
Hatakeyama, Susumi
Irie, Hiroshi
Miyashita, Masaaki
The enal 15 was synthesized in enantiomerically pure form starting from (S)-3-benzyloxy-2-methylpropanol 3 via highly regio- and stereo-selective methylation of the γ,δ-epoxy acrylate 5 with trimethylaluminium in the presence of water, developing an enantiospecific route to tirandamycin B.
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(2011)
