175698-87-0

Upstream product

• 1121-60-4 pyridine-2-carbaldehyde 

Downstream Products

• 175698-81-4 IrH₂(P(C₆D₅)3)2(NC₅H₄CHNC₆H₄OH)⁽¹⁺⁾*BF₄^(1-)=[IrH₂(P(C₆D₅)3)2(NC₅H₄CHNC₆H₄OH)]BF₄ 
• 175698-85-8 IrH₂(P(C₆D₅)3)2(NC₅H₄CHNC₆H₄OH)⁽¹⁺⁾*BF₄^(1-)=[IrH₂(P(C₆D₅)3)2(NC₅H₄CHNC₆H₄OH)]BF₄ 

Relevant academic research and scientific papers

An η1-Aldehyde Complex and the Role of Hydrogen Bonding in Its Conversion to an η1-Imine Complex

2-Pyridinecarboxaldehyde displaces Me2CO from [IrH2(Me2CO)2(PPh3) 2]+ to give a chelating N,O-bound product containing an η1-O-bound aldehyde group. This is converted to the η1-N-bound imine complex with a variety of substituted amines. When the amine contains a suitably positioned -OH group, intramolecular O-H?H-Ir dihydrogen bonds are detected in the products. This hydrogen bonding influences the relative rates of product formation from 2- and 4-aminophenol (rate ratio 6:1), where only the 2-isomer is capable of forming an intramolecular H-bond.