175774-37-5Relevant articles and documents
2,3-Dioxabicyclooct-5-ene: A Pyramidalized Olefin Whose Facial Selectivity Does Not Parallel Its Pyramidalization
Gandolfi, Remo,Tonoletti, Gisa,Rastelli, Augusto,Bagatti, Marisa
, p. 6038 - 6048 (1993)
The HF/3-21G-optimized geometry of 2,3-dioxabicyclooct-5-ene (1) shows that its olefinic hydrogens are bent in the syn direction (with respect to the dioxy bridge) by 2.1 deg, thus giving rise to anti pyramidalization of the doubly-bonded carbon at