175792-75-3Relevant academic research and scientific papers
Cycloaddition of homochiral dihydroimidazoles: A 1,3-dipolar cycloaddition route to optically active pyrrolo[1,2-a]imidazoles
Jones, Raymond C. F.,Howard, Kevin J.,Snaith, John S.,Blake, Alexander J.,Li, Wang-Shei,Steel, Peter J.
experimental part, p. 297 - 306 (2011/02/23)
N-Alkylation of optically active 1-benzyl-4-phenyl-4,5-dihydroimidazole with active alkyl halides and treatment of the so-formed 4,5-dihydroimidazolium ions with DBU in the presence of a range of electron-deficient alkene dipolarophiles, constitutes a 'on
Cycloaddition of homochiral imidazolinium ylides: A route to optically active pyrroloimidazoles
Jones, Raymond C. F.,Howard, Kevin J.,Snaith, John S.
, p. 1707 - 1710 (2007/10/03)
The synthesis of either enantiomer of 1-benzyl-4-phenyl-2-imidazoline from phenylglycine is described. 'One-pot' generation and enantioselective 1,3-dipolar cycloaddition of homochiral azomethine ylides prepared from these imidazolines with a range of alkene dipolarophiles affords optically active hexahydropyrroloimidazole adducts.
