175793-13-2

Upstream product

• 175792-75-3 (3S,5S,7R,7aS)-1-benzyl-5-tert-butoxycarbonyl-7-methoxycarbonyl-7-methyl-3-phenylhexahydropyrrolo[1,2-a]imidazole 
• 175792-86-6 (2S,4R)-1-[(S)-2-benzylamino-1-phenylethyl]-2-tert-butoxycarbonyl-4-methoxycarbonyl-4-methylpyrrolidine 
• 175792-98-0 (2S,4R)-2-tert-butoxycarbonyl-4-methoxycarbonyl-4-methylpyrrolidine 
• 175793-12-1 (2S,4R)-1-benzyloxycarbonyl-2-tert-butoxycarbonyl-4-methoxycarbonyl-4-methylpyrrolidine 
• 176739-83-6 (2S,4R)-1-benzyloxycarbonyl-4-methoxycarbonyl-4-methylpyrrolidine-2-carboxylic acid 
• 501-53-1 benzyl chloroformate 

Downstream Products

• 175793-15-4 (2S,4R)-1-benzyloxycarbonyl-2-(2-ethoxycarbonyl-(E)-ethenyl)-4-methoxycarbonyl-4-methylpyrrolidine 
• 175793-14-3 (2S,4R)-1-benzyloxycarbonyl-2-formyl-4-methoxycarbonyl-4-methylpyrrolidine 

Relevant academic research and scientific papers

An enantioselective route to pyrrolidines: Removal of the chiral template from homochiral pyrroloimidazoles

Two-step reductive removal of the chiral template from optically active pyrroloimidazoles, available from 1,3-dipolar cycloaddition of homochiral 4,5-dihydroimidazolium ylides, gives optically active substituted pyrrolidines. Selective manipulation of the substituents affords, e.g., naturally occurring and other optically active proline derivatives, and optically active pyrrolizidines and indolizidines.

An enantioselective route to pyrrolidines: Removal of the chiral template from homochiral pyrroloimidazoles

Two-step reductive removal of the chiral template from optically active pyrroloimidazoles, available from 1,3-dipolar cycloaddition of homochiral imidazolinium ylides, gives optically active substituted pyrrolidines. Selective manipulation of the substituents affords, e.g. naturally occurring proline derivatives and homochiral pyrrolizidines.