175849-92-0

Basic information

• Product Name: (+/-)-N-(4-Bromopentan-2-yl)oxazolidine-2,4-dione
• Synonyms: (+/-)-N-(4-Bromopentan-2-yl)oxazolidine-2,4-dione
• CAS NO: 175849-92-0
• Molecular Weight: 250.092
• Mol File: 175849-92-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (+/-)-N-(4-Bromopentan-2-yl)oxazolidine-2,4-dione(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-N-(4-Bromopentan-2-yl)oxazolidine-2,4-dione(175849-92-0)
• EPA Substance Registry System: (+/-)-N-(4-Bromopentan-2-yl)oxazolidine-2,4-dione(175849-92-0)

Safety Data

• Hazardous Substances Data: 175849-92-0(Hazardous Substances Data)

Upstream product

• 2346-26-1 2,4-oxazolidinedione 
• 76137-48-9 (+/-)-4-Bromopentan-2-ol 

Relevant articles and documents

Highly diastereoselective route to trans-S-substituted 2-hydroxymethylpyrrolidine derivatives by radical cyclisation

The cyclisation of radical species generated from (S)-N-(3-bromopropyl)oxazolin-2-ones 22 by treatment with tributylstannane in the presence of AIBN yielded 5-substituted pyrrolooxazolones with high diastereoselectivity. In the same reaction using (±)-N-(3-bromobutyl)oxazolin-2-one 25a or (±)-N-(4-bromopentan-2-yl)oxazolin-2-one 25b, the radical cyclisation gave predominantly the (5S*,7S*,7aR*)-5,7-disubstituted pyrrolooxazolines rather than the (5S*,7R*,7aR*) products. The radical cyclisation of 4-phenylsulfanyloxazolidinones 29a,b also resulted in the predominant formation of the corresponding (5S,7S,7aR)-5,7-disubstituted pyrrolooxazolidine derivatives.