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2-(diphenylphosphinoyl)piperidine is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

175857-65-5

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175857-65-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 175857-65-5 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,7,5,8,5 and 7 respectively; the second part has 2 digits, 6 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 175857-65:
(8*1)+(7*7)+(6*5)+(5*8)+(4*5)+(3*7)+(2*6)+(1*5)=185
185 % 10 = 5
So 175857-65-5 is a valid CAS Registry Number.

175857-65-5Relevant academic research and scientific papers

A new synthetic route to 2-alkyl-4-aryl-1(2H)-isoquinolones and 2-alkyl-4-aryl-1,2,3,4-tetrahydroisoquinolines

Couture, Axel,Deniau, Eric,Grandclaudon, Pierre,Woisel, Patrice

, p. 4433 - 4448 (1996)

4-Aryl and heteroaryl-1(2H)-isoquinolones have been prepared by base promoted cyclization of phosphorylated o-aroyl and heteroaroyl benzamides. Subsequent reduction of the carbonyl and styryl functions of the annulated products has given rise to 4-aryl-1,2,3,4-tetrahydroisoquinolines.

Synthesis of bicyclic carbamates as precursors of Sedum alkaloid derivatives

Szakonyi, Zsolt,D'Hooghe, Matthias,Kanizsai, Iván,Fül?p, Ferenc,De Kimpe, Norbert

, p. 1595 - 1602 (2007/10/03)

Synthesis of a N-Boc-protected piperidin-2-yl phosphine oxide starting from piperidine in three steps, followed by olefination using a variety of α,β-unsaturated aldehydes resulted in tert-butyl 2-(2′- alkenylidene)piperidine-1-carboxylates in high yields

First synthesis and pharmacological evaluation of benzoindolizidine and benzoquinolizidine analogues of α- and β-peltatin

Couture, Axel,Deniau, Eric,Grandclaudon, Pierre,Lebrun, Stephane,Leonce, Stephane,Renard, Pierre,Pfeiffer, Bruno

, p. 2113 - 2125 (2007/10/03)

The benzoindolizidine and-quinolizidine analogues of α- and β-peltatin were designed and synthesized by two different synthetic routes involving as the key step the Bischler-Napieralski cyclization of suitably substituted N-acyl-2-arylmethylpyrrolidine and -piperidine derivatives. The in vitro biological activity of these analogues as well as some of their derivatives was subsequently evaluated. Copyright (C) 2000 Elsevier Science Ltd.

An efficient synthesis of 5-(or 6-)-arylbenzoindolizidine and - quinolizidine derivatives

Lebrun, Stephane,Couture, Axel,Deniau, Eric,Grandclaudon, Pierre

, p. 2345 - 2352 (2007/10/03)

A new methodology for the synthesis of (hetero)arylated benzomdolizidine and benzoquinolizidine derivatives through sequential reduction of pyrrolidine- and piperidine-based aromatic enamides, and ultimate cyclization, is reported.

Dramatically different photochemical behaviour of 1-aroyl-2-methylene piperidine and pyrrolidine derivatives. An expeditious synthesis of ruspolinone

Couture,Deniau,Grandclaudon,Lebrun

, p. 7749 - 7752 (2007/10/03)

Upon irradiation in neutral solvent, the diversely substituted 1-aroyl-2-methylenepiperidines 6a-f give rise to photocyclized products 4a-f while their pyrrolidine congeners 7a,c,d afford enaminoketones 18a,c,d products of photo-Fries rearrangement.

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