175890-06-9

Basic information

• Product Name: (+/-)-2-diphenylphosphino-1,1'-(1-N,N-dimethylaminopropane-1,3-diyl)ferrocene
• CAS NO: 175890-06-9
• Molecular Weight: 453.347
• Mol File: 175890-06-9.mol

Chemical Properties

• CAS DataBase Reference: (+/-)-2-diphenylphosphino-1,1'-(1-N,N-dimethylaminopropane-1,3-diyl)ferrocene(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-2-diphenylphosphino-1,1'-(1-N,N-dimethylaminopropane-1,3-diyl)ferrocene(175890-06-9)
• EPA Substance Registry System: (+/-)-2-diphenylphosphino-1,1'-(1-N,N-dimethylaminopropane-1,3-diyl)ferrocene(175890-06-9)

Safety Data

• Hazardous Substances Data: 175890-06-9(Hazardous Substances Data)

Upstream product

• 64440-46-6 (+/-)-1,1'-(1-N,N-dimethylaminopropane-1,3-diyl)ferrocene 
• 1079-66-9 chloro-diphenylphosphine 

Downstream Products

• 911126-35-7 (((C₆H₅)2PC₅H₃CH(N(CH₃)2)CH₂CH₂C₅H₄)Fe)RuCl₂(P(C₆H₅)3) 
• 214825-62-4 ((C₅H₄C₂H₄CHN(CH₃)2C₅H₃P(C₆H₅)2)Fe)Pd(CH₃)2 
• 214825-66-8 ((C₅H₄C₂H₄CHN(CH₃)2C₅H₃P(C₆H₅)2)Fe)Pd(C₄H₂O₃) 
• 214825-61-3 ((C₅H₄C₂H₄CHN(CH₃)2C₅H₃P(C₆H₅)2)Fe)Pd(CH₃)Cl 
• 214825-69-1 ((C₅H₄C₂H₄CHN(CH₃)2C₅H₃P(C₆H₅)2)Fe)Pd(C₃H₄CH₃)⁽¹⁺⁾*OSO₂CF₃^(1-)=[(C₂₇H₂₈NP)FePd(C₃H₄CH₃)]OSO₂CF₃ 
• 214825-63-5 ((C₅H₄C₂H₄CHN(CH₃)2C₅H₃P(C₆H₅)2)Fe)Pd(C₆F₅)2 
• 258523-64-7 RuClH(C₈H₁₂)(Fe(C₂₇H₂₈NP)) 

Relevant articles and documents

Isomeric diphosphines of a heteroannularly bridged ferrocene: Preparation, chromatographic separation and structure elucidation

Twofold lithiation of the heteroannularly bridged aminophosphine 5 yielded a mixture of five isomeric aminodiphosphines 7a-7d and 11, which were separated by adsorption chromatography. Their substitution pattern was elucidated by X-ray structure analyses and chemical correlation. Corresponding diphosphines 10a-10d were derived with moderate yields via acetates 8a-8d. A search for stable conformers of 7a-7d and 11 was conducted using empirical force field calculations. Calculated minimum-energy geometries were compared with crystal structures of 7a, 7c and 7d.