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17596-79-1 Usage


(S)-2-Phenyl-1-propylamine is an organic compound that serves as a crucial building block in the synthesis of various pharmaceutical compounds. It is a chiral amine with a phenyl group and a propyl chain, which contributes to its unique chemical properties and reactivity.


Used in Pharmaceutical Industry:
(S)-2-Phenyl-1-propylamine is used as a key intermediate in the synthesis of pyrazolyl-containing tricyclic derivatives, which are known for their potential as anticancer agents. These derivatives target specific cellular pathways, exhibiting inhibitory effects on tumor growth and progression.
Used in Enantioselective Synthesis:
In the field of organic chemistry, (S)-2-Phenyl-1-propylamine is utilized as a building block for the enantioselective synthesis of pyrizinostatin. Pyrizinostatin is a pyroglutamyl peptidase inhibitor, which has potential applications in the development of novel therapeutics for various diseases.

Check Digit Verification of cas no

The CAS Registry Mumber 17596-79-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,7,5,9 and 6 respectively; the second part has 2 digits, 7 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 17596-79:
151 % 10 = 1
So 17596-79-1 is a valid CAS Registry Number.

17596-79-1 Well-known Company Product Price

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  • (Code)Product description
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  • TCI America

  • (M1747)  (S)-(-)-β-Methylphenethylamine  >98.0%(GC)(T)

  • 17596-79-1

  • 5g

  • 850.00CNY

  • Detail
  • TCI America

  • (M1747)  (S)-(-)-β-Methylphenethylamine  >98.0%(GC)(T)

  • 17596-79-1

  • 25g

  • 2,850.00CNY

  • Detail
  • Aldrich

  • (461393)  (S)-β-Methylphenethylamine  99%

  • 17596-79-1

  • 461393-1G

  • 1,458.99CNY

  • Detail



According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 20, 2017

Revision Date: Aug 20, 2017


1.1 GHS Product identifier

Product name (S)-2-Phenyl-1-propylamine

1.2 Other means of identification

Product number -
Other names (S)-(-)-Beta-Methylphenethylamine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:17596-79-1 SDS

17596-79-1Relevant articles and documents



, p. 564,566 (1943)




, p. 1449,1450 (1942)


CO2-Assisted asymmetric hydrogenation of prochiral allylamines

Alridge, Christopher J.,De Winter, Tamara M.,Ho, Jaddie,Jessop, Philip G.

, p. 6755 - 6761 (2022/03/31)

A new methodology for the asymmetric hydrogenation of allylamines takes advantage of a reversible reaction between amines and carbon dioxide (CO2) to suppress unwanted side reactions. The effects of various parameters (pressure, time, solvent, and base additives) on the enantioselectivity and conversion of the reaction were studied. The homogeneously-catalyzed asymmetric hydrogenation of 2-arylprop- 2-en-1-amine resulted in complete conversion and up to 82% enantiomeric excess (ee). Added base, if chosen carefully, improves the enantioselectivity and chemoselectivity of the overall reaction.

Enantioselective Synthesis of β-Methyl Amines via Iridium-Catalyzed Asymmetric Hydrogenation of N-Sulfonyl Allyl Amines

Cabré, Albert,Verdaguer, Xavier,Riera, Antoni

, p. 4196 - 4200 (2019/08/16)

The iridium-catalyzed asymmetric hydrogenation of several N-sulfonyl allyl amines is reported. All substrates can be easily obtained by the Ir-catalyzed isomerization of N-tosylaziridines reported previously. The commercially available threonine-derived phosphinite (UbaPHOX) iridium complex has been found to be the best catalyst for this catalytic application, affording β-methyl amines with good to excellent ee values (up to 94%). The synthetic potential of this novel methodology was demonstrated by the formal synthesis of Lorcaserin and LY-404187. (Figure presented.).

Biocatalytic Formal Anti-Markovnikov Hydroamination and Hydration of Aryl Alkenes

Wu, Shuke,Liu, Ji,Li, Zhi

, p. 5225 - 5233 (2017/08/17)

Biocatalytic anti-Markovnikov alkene hydroamination and hydration were achieved based on two concepts involving enzyme cascades: epoxidation-isomerization-amination for hydroamination and epoxidation-isomerization-reduction for hydration. An Escherichia coli strain coexpressing styrene monooxygenase (SMO), styrene oxide isomerase (SOI), ω-transaminase (CvTA), and alanine dehydrogenase (AlaDH) catalyzed the hydroamination of 12 aryl alkenes to give the corresponding valuable terminal amines in high conversion (many ≥86%) and exclusive anti-Markovnikov selectivity (>99:1). Another E. coli strain coexpressing SMO, SOI, and phenylacetaldehyde reductase (PAR) catalyzed the hydration of 12 aryl alkenes to the corresponding useful terminal alcohols in high conversion (many ≥80%) and very high anti-Markovnikov selectivity (>99:1). Importantly, SOI was discovered for stereoselective isomerization of a chiral epoxide to a chiral aldehyde, providing some insights on enzymatic epoxide rearrangement. Harnessing this stereoselective rearrangement, highly enantioselective anti-Markovnikov hydroamination and hydration were demonstrated to convert α-methylstyrene to the corresponding (S)-amine and (S)-alcohol in 84-81% conversion with 97-92% ee, respectively. The biocatalytic anti-Markovnikov hydroamination and hydration of alkenes, utilizing cheap and nontoxic chemicals (O2, NH3, and glucose) and cells, provide an environmentally friendly, highly selective, and high-yielding synthesis of terminal amines and alcohols.

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