176018-27-2Relevant academic research and scientific papers
SET-photosensitized reactions of α-silylamino-enones and ynones proceeding by 6-endo α-amino radical cyclization pathways
Khim, Seock-Kyu,Cederstrom, Ericka,Ferri, Dino C.,Mariano, Patrick S.
, p. 3195 - 3222 (2007/10/03)
SET-photosensitized reactions of α,β-enones and -ynones containing tethered α-silylamine functions are described. The processes lead to hydropyridine ring construction via pathways involving 6-endo type α-amino radical cyclizations. High degrees of regio- and stereocontrol attend these reactions.
A novel method for synthesis of functionalized piperidines
Khim, Seock Kyu,Mariano, Patrick S.
, p. 999 - 1002 (2007/10/02)
A new methodology for synthesis of functionalized piperidines which employs photoinduced radical cyclization of α-silylamino-enones and ynones is described.
