176101-72-7Relevant academic research and scientific papers
A mild oxidation of nitrile oxides: A new synthetic route to nitroso carbonyl intermediates
Quadrelli,Gamba Invernizzi,Caramella
, p. 1909 - 1912 (1996)
Addition of N-methyl morpholine N-oxide (NMO) to a nitrile oxide solution in dichloromethane at room temperature in the presence of a diene affords nitroso carbonyl adducts in fair yields.
The mild oxidation of nitrile oxides affords a convenient entry to nitrosocarbonyl intermediates, versatile tools in organic syntheses
Quadrelli,Mella,Gamba Invernizzi,Caramella
, p. 10497 - 10510 (2007/10/03)
Nitrile oxides are oxidized by tertiary amine N-oxides in different solvents at room temperature to afford in the presence of dienes nitrosocarbonyl adducts in fair yields. The mild conditions used in oxidizing a variety of nitrile oxides promise a wide application of this method in synthetic processes.
