176107-88-3

Upstream product

• 135897-92-6 ethyl (2E,6E)-8-hydroxy-2,6-dimethylocta-2,6-dienoate 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 107905-52-2 ethyl 2-[bis(2,2,2-trifluoroethyl)phosphono]propionate 
• 139109-02-7 (E)-6-((tert-butyldiphenylsilyl)oxy)-4-methylhex-4-enal 

Downstream Products

• 916754-49-9 (2E,6E)-8-[t-butyl(diphenyl)silyl]oxy-2,6-dimethyl-2,6-octadien-1-ol-1,1-d₂ 
• 117638-13-8 (Δ^2,3E,Δ^6,7E)-1-O-tert-butyldiphenylsilyl-3,7-dimethyl-octa-2,6-dien-1,8-diol 
• 176107-79-2 Benzoic acid (2R,3S,6S)-6-((R)-2-acetoxy-1-hydroxy-ethyl)-2-but-3-enyl-2,6-dimethyl-tetrahydro-pyran-3-yl ester 
• 1027080-08-5 Benzoic acid (E)-(S)-6-(tert-butyl-diphenyl-silanyloxy)-1-((R)-1-hydroxy-1-methyl-pent-4-enyl)-4-methyl-hex-4-enyl ester 
• 176107-80-5 Benzoic acid (2R,3S,6S)-6-((R)-2-acetoxy-1-methanesulfonyloxy-ethyl)-2-but-3-enyl-2,6-dimethyl-tetrahydro-pyran-3-yl ester 
• 1053716-79-2 Benzoic acid (2R,3S,6R,7S)-2-but-3-enyl-6-hydroxy-7-hydroxymethyl-2,6-dimethyl-oxepan-3-yl ester 

Relevant academic research and scientific papers

Biomimetic synthesis of (±)-pinnatal and (±)-sterekunthal A

Concise biomimetic syntheses of the antimalarial naphthoquinones (±)-pinnatal and (±)-sterekunthal A are described. Copyright

Stereoselective synthesis of the S- and Y-ring systems of maitotoxin

The seven-membered S- and Y-ring systems of maitotoxin (1) were stereoselectively synthesized based on the rearrangement-ring expansion of the six-membered ethers having the mesylate group on the α-side chain.