916754-49-9

Upstream product

• 139109-02-7 (E)-6-((tert-butyldiphenylsilyl)oxy)-4-methylhex-4-enal 
• 202339-11-5 (E)-tert-butyl{[5-(3,3-dimethyloxiran-2-yl)-3-methylpent-2-en-1-yl]oxy}diphenylsilane 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 139109-03-8 tert-butyl ({[(2E)-3,7-dimethylocta-2,6-dien-1-yl]oxy})diphenylsilane 
• 106-24-1 Geraniol 
• 916754-48-8 methyl (2E,6E)-8-[t-butyl(diphenyl)silyl]oxy-2,6-dimethyl-2,6-octadienoate 
• 176107-88-3 8-(tert-butyldiphenylsilanyloxy)-2,6-dimethylocta-2,6-dienoic acid ethyl ester 

Downstream Products

• 916754-53-5 (2E,6E)-8-[t-butyl(diphenyl)silyl]oxy-2,6-dimethyl-2,6-octadienyl-1,1-d₂ 1-methanesulfonate 
• 916754-54-6 (E,E)-1-t-butyldiphenylsilyloxy-3,7-dimethyl-2,6-octadiene-8,8,8-d₃ 

Relevant academic research and scientific papers

Facile synthesis of deuterium-labelled geranylgeraniols

Facile and stereoselective syntheses of three different kinds of deuterium-labelled geranylgeraniol analogs have been achieved. LiAlD4 is used as the deuterium source to ensure high deuterium incorporation. [8,8-d2]- and [9,9-d2]- geranylgeraniols have been prepared for the first time. [10-d]- geranylgeraniol was efficiently prepared with a high degree of deuterium incorporation.

Stereoselective disposition of the geminal dimethyl group in the cyclization of geranyl acetate under zeolite confinement conditions

The stereochemistry in the acid-catalysed biomimetic cyclization of [8,8,8-D3]geranyl acetate was examined in solution and under conditions of zeolite Y confinement. In the intrazeolite reaction the gem-allylic methyl group adopts a diastereose