17618-76-7Relevant articles and documents
Upgrading 1-butanol to unsaturated, carbonyl and aromatic compounds: A new synthesis approach to produce important organic building blocks
Boscolo, Mauricio,Metzker, Gustavo,Mora Vargas, Jorge,Orduna Ortega, Julieth,Tofaneli Morelato, Luiz Henrique
supporting information, p. 2365 - 2369 (2020/05/13)
Unsaturated, carbonyl and aromatic products were obtained by reacting 1-butanol or a 1-butanol:methanol mixture with a copper mixed metal oxide catalyst in a fixed bed reactor. The selectivities observed, mostly for the unsaturated and carbonyl products, can represent a new alternative and greener pathway for the production of fine-chemicals and organic building blocks.
HOMOALLYLIC SUBSTITUTION REACTIONS OF LITHIUM DIALKYL CUPRATES WITH CYCLOPROPYLCARBINYL HALIDES: MECHANISTIC CONSIDERATIONS
Hrubiec, Robert T.,Smith, Michael B.
, p. 1457 - 1468 (2007/10/02)
Highly reactive lithium dialkyl cuprates and 1-bromo-1-cyclopropylalkanes, 4, react to give good yields of the homoallylic substitution product, 6.Less reactive organocuprates react with 4 to give mixtures of 6 and the direct substitution product 7.These results are consistent with a copper(I) radical intermediate which undergoes facile rearrangement prior to reductive coupling.
