17619-06-6

Basic information

• Product Name: Phenol, 2,2'-(phenylmethylene)bis[6-(1,1-dimethylethyl)-4-methyl-
• CAS NO: 17619-06-6
• Molecular Formula: C29H36O2
• Molecular Weight: 416.604
• Mol File: 17619-06-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Phenol, 2,2'-(phenylmethylene)bis[6-(1,1-dimethylethyl)-4-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Phenol, 2,2'-(phenylmethylene)bis[6-(1,1-dimethylethyl)-4-methyl-(17619-06-6)
• EPA Substance Registry System: Phenol, 2,2'-(phenylmethylene)bis[6-(1,1-dimethylethyl)-4-methyl-(17619-06-6)

Safety Data

• Hazardous Substances Data: 17619-06-6(Hazardous Substances Data)

Upstream product

• 106-44-5 p-cresol 
• 1634-04-4 tert-butyl methyl ether 
• 100-52-7 benzaldehyde 
• 2409-55-4 2-tert-Butyl-4-methylphenol 

Relevant articles and documents

2. 2' - Benzyl - different substituted [...] ethyl aluminum compound and its preparation method

The invention relates to a 2, 2' - benzyl - different substituted [...] ethyl aluminum compound and its preparation method, its preparation method is as follows: the benzaldehyde and containing different substituent of the phenol to the molar ratio of 1:2

Optimization of asymmetric catalysts using achiral ligands: metal geometry-induced ligand asymmetry.

[reaction: see text] Traditionally, asymmetric catalysts have been optimized by modification of resolved chiral ligands. In this Letter, we optimize the asymmetric addition of diethylzinc to aldehydes by modification of achiral methylene bis(phenol) ligands. Upon coordination of the substrate, the achiral ligand becomes asymmetric, a concept termed Metal Geometry-Induced Ligand Asymmetry. The enantioselectivity of the catalyst formed from a single resolved ligand and several achiral ligands ranged from 9% (R) to 83% (S).