176248-72-9

Upstream product

• 38460-95-6 undec-10-enoyl chloride 
• 111-81-9 Methyl 10-undecenoate 
• 54704-39-1 (+/-)-10-Hydroxyundecansaeure-methylester 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 68820-37-1 10-methylundecan-1-al 
• 20194-45-0 10-methyl-1-undecanol 

Relevant academic research and scientific papers

Cobalt-Catalyzed Intermolecular Markovnikov Hydroamination of Nonactivated Olefins: N2-Selective Alkylation of Benzotriazole

Cobalt-catalyzed Markovnikov-selective hydroamination of nonactivated olefins was developed. Hydrogen atom transfer from a catalytically generated cobalt(III)-hydride complex to the olefins proceeded regioselectively, and the nucleophilic addition of benzotriazoles occurred selectively at their N2-positions. The synthetic utility of the obtained N2-alkylated benzotriazoles as stable amine protecting groups under various reaction conditions was demonstrated, and the products were also transformed into primary amines by zinc-mediated reduction.

Synthesis of racemic lipid unit of the nucleoside antibiotic, liposidomycin-B

The lipid part (10) of liposidomycin-B has been synthesised through functional manipulation of undecenoic acid (1) which involves chain extension via Reformatsky reaction and introduction of the methyl branching through organocuprate coupling.