176434-82-5

Basic information

• Product Name: tetraphenylphosphonium bromobis(diethyldithiocarbamato-S,S')cadmium(II)
• CAS NO: 176434-82-5
• Molecular Weight: 828.257
• Mol File: 176434-82-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tetraphenylphosphonium bromobis(diethyldithiocarbamato-S,S')cadmium(II)(CAS DataBase Reference)
• NIST Chemistry Reference: tetraphenylphosphonium bromobis(diethyldithiocarbamato-S,S')cadmium(II)(176434-82-5)
• EPA Substance Registry System: tetraphenylphosphonium bromobis(diethyldithiocarbamato-S,S')cadmium(II)(176434-82-5)

Safety Data

• Hazardous Substances Data: 176434-82-5(Hazardous Substances Data)

Upstream product

• 14239-68-0 cadmium(II) diethyldithiocarbamate 
• 2751-90-8 tetraphenylphosphonium bromide 

Relevant articles and documents

The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br]

The title compounds, tetraphenylphosphonium chlorobis(diethyldithiocarbamato-S,S)cadmium(II), (C24H20P)-[CdCl(C5H10NS 2)2], (1), and tetraphenylphosphonium bromobis(diethyldithiocarbamato-S,S)cadmium(II), (C24-H20P)[CdBr(C5H10NS 2)2], (2), are isomorphous. The compexes are mononuclear with coordination spheres of the types S4Cl and S4Br, respectively. The central Cd atom is linked to four S atoms and two bidentate dithiocarbamate ligands and to the halide atom. The resulting Cd-atom coordination geometry is halfway between trigonal bipyrimidal and square pyramidal. Principal dimensions include: Cd-S 2.573 (1)-2.682 (1) in (1) and 2.571 (3)-2.736 (2) A in (2); Cd-Cl and Cd-Br 2.462 (1) and 2.626 (1) A, respectively.