14239-68-0

Basic information

• Product Name: Cadmium diethyldithiocarbamate
• Synonyms: ai3-26109;bis(diethylcarbamodithioato-S,S’)-,(T-4)-Cadimium;bis(diethyldithiocarbamate)cadmium;bis(diethyldithio-carbamate)cadmium;bis(diethyldithiocarbamato)-cadmiu;Bis(diethyldithiocarbamato)cadmium;Cadmate;Cadmium bis(N,N-diethyldithiocarbamate)
• CAS NO: 14239-68-0
• Molecular Formula: C₁₀H₂₀CdN₂S₄
• Molecular Weight: 408.95
• EINECS: 238-113-4
• Product Categories: Organometallics
• Mol File: 14239-68-0.mol
• Article Data: 6

Chemical Properties

• Melting Point: 63-69°C (dec.)
• Boiling Point: 94.3°C
• Flash Point: 60.5 °C
• Appearance: /
• Density: 1,48 g/cm3
• CAS DataBase Reference: Cadmium diethyldithiocarbamate(CAS DataBase Reference)
• NIST Chemistry Reference: Cadmium diethyldithiocarbamate(14239-68-0)
• EPA Substance Registry System: Cadmium diethyldithiocarbamate(14239-68-0)

Safety Data

• Statements: 20/21/22-51/53
• Safety Statements: 22-26-28-45
• RIDADR: 2570
• TSCA: Yes
• HazardClass: 6.1(b)
• PackingGroup: III
• Hazardous Substances Data: 14239-68-0(Hazardous Substances Data)

Usage

Uses

Cadmium Diethyldithiocarbamate can be used for a photocatalytic hydrogen production promoter.

Safety Profile

Confirmed human carcinogenwith experimental tumorigenic data. Mutation datareported. When heated to decomposition it emits verytoxic fumes of NOx and SOx.

InChI:InChI=1/2C5H11NS2.Cd/c2*1-3-6(4-2)5(7)8;/h2*3-4H2,1-2H3,(H,7,8);/q;;+2/p-2/rC10H20CdN2S4/c1-5-12(6-2)9(14)16-11-17-10(15)13(7-3)8-4/h5-8H2,1-4H3

Upstream product

• 75-15-0 carbon disulfide 
• 109-89-7 diethylamine 
• 7440-43-9 cadmium 
• 97-77-8 disulfiram 
• 20624-25-3 sodium diethyldithiocarbamate trihydrate 
• 10108-64-2 cadmium(II) chloride 
• 16110-84-2 Cd(ipxa)2 
• 125697-79-2 {Ph₃PCH₂Ph}{edtc} 
• 148-18-5 sodium N,N-diethyldithiocarbamate 
• 1518-58-7 diethylammonium diethyldithiocarbamate 

Downstream Products

• 16986-83-7 cadmium(II) propionate 
• 176434-81-4 tetraphenylphosphonium chlorobis(diethyldithiocarbamato-S,S')cadmium(II) 
• 176434-82-5 tetraphenylphosphonium bromobis(diethyldithiocarbamato-S,S')cadmium(II) 
• 14267-17-5 nickel(II) diethyldithiocarbamate 
• 14239-51-1 bis(N,N-diethyldithiocarbamato)mercury(II) 

Relevant articles and documents

Preparation of CdS-doped glasses from gels containing diethyldithiocarbamatocadmium

CdS-doped SiO2 glasses were prepared via silica gels containing diethyldithiocarbamatocadmium Cd(S2CN(C2H5)2)2. Heat treatment of the gels gave transparent yellow SiO2 glasses do

The use of single-source precursors for the solution-liquid-solid growth of metal sulfide semiconductor nanowires

(Figure Presented) All wired up! High-quality colloidal PbS and CdS nanowires were grown from Bi nanoparticles by the solution-liquid-solid (SLS) mechanism. The single-source-precursor strategy could provide a general approach for the synthesis of colloidal semiconductor nanowires.

Kinetic analysis of the decomposition of chelates of di-alkyldithiocarbamate of Cd(II)

The thermal decomposition kinetics of the solid complexes Cd(S2CNR2)2, where R=C2H5, n-C3H7, n-C4H9 or iso-C4H9, was studied by using isothermal and non-isothermal thermogravimetry. The super-imposed TG/DTG/DSC curves revealed that thermal decomposition reactions occur in the liquid phase. The kinetic model that best fitted the experimental isothermal TG data was the one-dimensional phase-boundary reaction-controlled process R1. The thermal analysis data suggested the thermal stability sequence Cd(S2CNBu2n)2>Cd(S2CNPr2n)2 >Cd(S2CNBu2i)2>Cd(S2CNEt2)2, which accords with the sequence of stability of the apparent activation energies.