17648-64-5Relevant academic research and scientific papers
New organotin(IV) chlorides derived from N-(2-hydroxyphenyl)aryloxy sulfamates. Synthesis, characterization and DSC investigation
Akremi, Ali,Noubigh, Adel
, (2019/01/30)
Abstract: Three monomeric pentacoordinate organotin complexes were prepared by the reaction of dimethyltin dichloride with three N-(2-hydroxy)phenyl substituted aryloxy sulfamates in alkaline medium. The newly synthesized compounds were characterized on the basis of their infrared, CPMAS NMR, powder XRD diffraction and elemental analysis. The XRD powder analyses revealed a tetragonal system for two complexes, whereas the third one was crystallized in the hexagonal system. The thermal decomposition behavior of the synthesized complexes have been investigated and all the organotin compounds have a similar order of thermal stability. Graphical Abstract : Synopsis We synthesized three organotin complexes 3a-c and have investigated their thermal properties. The XRD powder analyses revealed tetragonal system for two complexes, whereas the third one crystallized in hexagonal system. The differential scanning calorimetric data demonstrate high stability of all the synthesized complexes.[Figure not available: see fulltext.].
Synthesis of highly fluorinated aryl N -acylsulfamates and evaluation of their surfactant properties
Sbihi, Hassen,Ouahmi, Faouzia,Beji, Mohamed,Baklouti, Ahmed
, p. 539 - 544 (2013/07/25)
Reaction of highly fluorinated carboxylic acids with aroxysulfonylisocyanates in the presence of triethylamine allowed the preparation of the corresponding highly fluorinated aroxy-N-sulfonylsulfamates. The reaction proceeds with good yield in toluene at
