176541-05-2

Upstream product

• 176541-03-0 Acetic acid (R)-2-(2-methoxy-ethoxymethoxymethyl)-pent-4-enyl ester 
• 176541-04-1 (S)-2-(2-Methoxy-ethoxymethoxymethyl)-pent-4-en-1-ol 
• 100-39-0 benzyl bromide 
• 176540-99-1 [(S)-2-(2-Methoxy-ethoxymethoxymethyl)-pent-4-enyloxymethyl]-benzene 

Downstream Products

• 176541-07-4 Toluene-4-sulfonic acid (S)-4-benzyloxy-2-benzyloxymethyl-butyl ester 
• 176541-01-8 (S)-4-benzyloxy-2-(benzyloxymethyl)-1-iodobutane 
• 176541-06-3 (R)-4-Benzyloxy-2-benzyloxymethyl-butan-1-ol 
• 176541-00-7 (S)-4-benzyloxy-2-(benzyloxymethyl)-1-[(2-methoxyethoxy)methoxy]butane 

Relevant academic research and scientific papers

Asymmetric Bis(alkoxycarbonylation) Reaction of Homoallylic Alcohols Catalyzed by Palladium in the Presence of Cu(I) Triflate Using the Chiral Bioxazoline Ligand

Palladium-catalyzed asymmetric intra- and intermolecular bis(alkoxycarbonylation) reactions of homoallylic alcohols in the presence of copper(I) triflate were achieved by using the chiral bioxazoline ligand, (S,S)-4,4′-dibenzyl-4,4′,5,5′-tetrahydro-2,2′-bioxazole, under normal pressure of carbon monoxide and oxygen at 25°C to give the corresponding optically active γ-butyrolactones in 19 - 65% ee.