17659-17-5Relevant articles and documents
Xanthates as Thiol Surrogates for Nucleophilic Substitution with Aryl Halides
Sokolov, Anatolii I.,Mikhaylov, Andrey A.,Baleeva, Nadezhda S.,Baranov, Mikhail S.
, p. 4350 - 4357 (2021/08/24)
We herein report an unprecedented xanthate-based protocol for the preparation of aryl-alkyl thioethers. Heating xanthates with aryl halides and namely cesium carbonate in methanol provides the target thioethers in generally good yields within short reaction times. This method allows one to avoid contact with odorous thiols and also to introduce substituents of which the corresponding thiols are virtually unavailable or inconvenient in use.
CYCLOKONDENSATIONEN VON O-ETHYL-S-SUBSTITUIERTEN DITHIOCARBONATEN ZU NEUEN 4-ALKYLTHIO-1,3-DITHIOL-2-THIONEN MIT HILFE VON SCHWEFELKOHLENSTOFF
Doelling, Wolfgang,Birkner, Vera,Perjessy, Alexander,Sustekova, Zora
, p. 223 - 232 (2007/10/02)
4-Alkylthio-5-(p-nitro-phenyl)-1,3-dithiole-2-thiones 4a-e, 4-alkylthio-5-(p- or o-cyano-phenyl)-1,3-dithiole-2-thiones 4f, 4g, 4-alkylthio-5-pivaloyl-1,3-dithiole-2-thiones 4h-j and 5-methylthio-2-thioxo-1,3-dithiole-4-carboxylic acid N-methyl-p-chloro-