176598-04-2Relevant academic research and scientific papers
Synthesis and structural characterisation of two η1-bonded N-phenylthioformamidate complexes of rhodium
McEneaney, Patricia A.,Spalding, Trevor R.,Ferguson, George
, p. 145 - 147 (2007/10/03)
The complexes [3-{η1-SC(H)NPh}-3,3-(PMe2Ph) 2-3,1,2-closo-RhC2B9H11] and [2-{η1-SC(H)NPh}-2,2-(PMe2Ph) 2-2,1-closo-RhTeB10H10] have been structurally characterised using X-ray crystallography and are the first η1-bonded thioformamidate complexes to be isolated.
An air-stable, cationic metallacarborane without a charge-compensated carborane ligand
Ferguson, George,Pollock, Jason,McEneaney, Patricia A.,O'Connell, Donnacha P.,Spalding, Trevor R.,Gallagher, John F.,Macias, Ramon,Kennedy, John D.
, p. 679 - 681 (2007/10/03)
The first air-stable, cationic rhodadicarborane complex, [3-(MeCN)-3,3-(PPh2Me)2-3,1,2-closo-RhC2B 9H11][SbF6] 1, which does not contain a 'charge-compensated' carborane ligand is synthesised and structurally characterised by X-ray crystallography and spectroscopic techniques (IR and NMR).
