17665-58-6

Basic information

• Product Name: Acetonitrile, (phenylsulfinyl)-
• Synonyms: HMS1529G11;cyanomethyl phenyl sulfoxide;Phenyl cyanomethyl sulfoxide;phenylsulphinyl acetonitrile
• CAS NO: 17665-58-6
• Molecular Formula: C8H7NOS
• Molecular Weight: 165.216
• Mol File: 17665-58-6.mol
• Article Data: 24

Chemical Properties

• CAS DataBase Reference: Acetonitrile, (phenylsulfinyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Acetonitrile, (phenylsulfinyl)-(17665-58-6)
• EPA Substance Registry System: Acetonitrile, (phenylsulfinyl)-(17665-58-6)

Safety Data

• Hazardous Substances Data: 17665-58-6(Hazardous Substances Data)

Upstream product

• 5219-61-4 (phenylthio)acetonitrile 
• 108-98-5 thiophenol 
• 930-69-8 sodium thiophenolate 

Downstream Products

• 139427-24-0 3,3-Bis(benzylthio)-2-(phenylsulfinyl)acrylonitril 
• 139427-23-9 3,3-Bis(methylthio)-2-(phenylsulfinyl)acrylonitril 
• 6612-79-9 phenyl (2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl) disulfide 
• 1206551-82-7 N-[(1,1-dimethylethoxy)carbonyl]-S-phenylthio-L-cysteine 
• 13153-10-1 1-(butylsulfinyl)benzene 
• 36638-55-8 1-(phenylthio)cyclohexanecarbonitrile 
• 1360557-39-6 1-(phenylsulfinyl)cyclohexanecarbonitrile 
• 5219-61-4 (phenylthio)acetonitrile 
• 139427-37-5 3-Amino-5-<(methoxycarbonyl)methylthio>-4-(phenylsulfinyl)-2-thiophencarbonsaeure-methylester 
• 125263-27-6 4-(phenylsulfonyl)-4-cyano-1-butene 
• 128766-70-1 Benzenesulfonyl-cyclopent-2-enyl-acetonitrile 
• 336195-87-0 (E)-4-hydroxy-5-phenylpent-2-enenitrile 

Relevant articles and documents

BIOMIMETIC OXIDATION OF ORGANIC SULFIDES WITH TPPFe(III)Cl/IMIDAZOLE/HYDROGEN PEROXIDE

An enzyme model system, consisted with TPPFe(III)Cl/imidazole has been found to catalyze hydrogen peroxide dependent S-oxygenation and oxidative S-dealkylation of organic sulfides.This biomimetic reaction has been compared with the cytochrome P-450 catalyzed H2O2 dependent oxygenation.

Tungstate supported mesoporous silica SBA-15 with imidazolium framework as a hybrid nanocatalyst for selective oxidation of sulfides in the presence of hydrogen peroxide

In this work, a new heterogeneous catalyst (SBA-15/Im/WO4 2?) was prepared, and then its performance in the oxidation of organic sulfides was studied (using 30% H2O2 as green oxidant under neutral reaction conditions). This organic–inorganic hybrid mesoporous material was characterized by various techniques, such as FT-IR, inductively coupled plasma, X-ray powder diffraction, high-resolution-transmission electron microscopy, N2 adsorption–desorption and thermogravimetric analysis. The catalyst was also applied to the selective oxidation of various sulfides. The hybrid catalyst was easily recovered, and was very stable and retained good activity for at least five successive runs without any additional activation. Moreover, there was no remarkable decrease in the activity and selectivity of the catalyst. The products could be easily isolated by just removing the solvent after filtering the catalyst. The yields of the catalytic productions through this catalyst were in the range from 75% to 97%.

A molybdenum based metallomicellar catalyst for controlled and selective sulfoxidation reactions in aqueous medium

A surfactant based molybdenum system that exhibits catalytic activity for sulfoxidation reactions of various organic sulfides in aqueous medium has been developed and comprehensively characterized using IR, XRD, NMR, ESI-MS, DLS and TEM. The catalyst showcases remarkable selectivity for the preparation of both sulfoxides and sulfones in the range of good to excellent yields. Furthermore, the catalyst showed a high degree of tolerance towards various sensitive functional groups such as hydroxyl, acetal, aldehyde, amine, imine, oxime, cyano and alkene. the Partner Organisations 2014.