176682-69-2

Upstream product

• 12107-36-7 sodium(η5-cyclopentadienyl)tricarbonyltungstate(II) 
• 84174-75-4 ClPhPN(SiMe₃)2 
• 213383-06-3 (C₅H₅)WCl(CO)2(PH(C₆H₅)N(Si(CH₃)3)2) 

Downstream Products

• 213383-13-2 (C₅H₅)WH(CO)2(P(C₆H₅)N(Si(CH₃)3)2)⁽¹⁺⁾*BF₄^(1-)=[(C₅H₅)WH(CO)2(P(C₆H₅)(N(Si(CH₃)3)2))]BF₄ 
• 213383-11-0 (C₅H₅)W(OCOCF₃)(CO)2(PH(C₆H₅)N(Si(CH₃)3)2) 
• 185676-15-7 (C₅H₅)W(S)(CO)2(P(C₆H₅)N(Si(CH₃)3)2) 
• 213383-08-5 (C₅H₅)WCl(CO)2(PH(C₆H₅)Cl) 
• 185676-17-9 (C₅H₅)W(Se)(CO)2(P(C₆H₅)N(Si(CH₃)3)2) 
• 1021953-25-2 (η(5)-C5H5)W(CO)2PHPPhN(SiMe3)2 

Relevant academic research and scientific papers

Reactions of protic reagents with a tungsten phosphenium ion complex

The reactions of metallophosphenium ion complex CpW(CO)2{P(Ph)[N(SiMe3)2]} with protic reagents HBF4, HCl, and CF3COOH have been studied. The 1:1 reactions result in protonation of the W=P bond, while the 1:2 reactions display cleavage of the P-N bond. The molecular structure of one product, Cp(CO)2(Cl)WP(H)(Ph)[N(SiMe3)2], was determined by single crystal X-ray diffraction techniques: triclinic space group P1 with a=9.6732(14) A, b=11.3419(15) A, c=11.5930(14) A, α=87.724(11)°, β=77.647(11)°, γ=82.989(11)°, V=1233.0(3) A3, Z=2.

Reactions of molybdenum and tungsten phosphenium complexes with sulfur and selenium

The reactions of the phosphane [(Me3Si)2N](Ph)PCl with NaCpMo(CO)3 and NaCpW(CO)3 give the respective metallophosphenium complexes Cp(CO)2M{P(Ph)[N(SiMe3)2]} (M = Mo (4a), W (4b)). The subsequent reactions of 4a,b with S and Se produce unexpectedly different products: Cp(CO)2(S)M{P(Ph)[N(SiMe3)2]} (M = Mo (7a)); Cp(CO)2MSP(Ph)[N(SiMe3)2] (M = W (7b)); Cp(CO)2MseP(Ph)[N(SiMe3)2] (M = Mo (8a), W (8b)). The compounds have been fully characterized by elemental analyses and spectroscopic data, and the molecular structures of 4a, 7a,b, and 8a have been determined by single-crystal X-ray diffraction techniques. The molecular structure of 7a displays a long, terminal Mo-S bond, while 7b and 8a contain M-E-P three-membered rings.