1769-47-7Relevant academic research and scientific papers
Flash chemistry using trichlorovinyllithium: Switching the reaction pathways by high-resolution reaction time control
Nagaki, Aiichiro,Takahashi, Yusuke,Henseler, Andrea,Matsuo, Chika,Yoshida, Jun-Ichi
supporting information, p. 214 - 216 (2015/03/05)
High-resolution reaction time control in flow microreactors enables the reaction-pathway switching of trichlorovinyllithium generated by the H/Li exchange of trichloroethene. The method was successfully app lied to the synthesis of 1,1,2-trichloroalkenes,
Synthesis of functional derivatives of aryl trichlorovinyl (trichloroallyl) ketones via consecutive transformations of the carbonyl group
Potkin,Petkevich,Kletskov,Dikusar,Rozentsveig,Levkovskaya
, p. 1412 - 1421 (2015/02/19)
An efficient procedure have been developed for the selective reduction of the carbonyl group in phenyl trichlorovinyl ketone and aryl trichloroallyl ketones by the action of NaBH4 in propan-2-ol to obtain the corresponding alcohols. The hydroxy
Thermally Unstable Allenes, XII. (1,3,3-Trichloro-1,2-propadienyl)benzene
Roedig, Alfred,Detzer, Norbert
, p. 2374 - 2376 (2007/10/02)
The thermally unstable allene 4 is prepared from the ketone 1 via the intermediates 2 and 3.It dimerizes at room temperature to 5, whose structure is proven by permanganate degradation.
