176965-56-3Relevant academic research and scientific papers
D-Xylose derived oxazolidin-2-ones as chiral auxiliaries in stereoselective acylations and halogenations
Luetzen, Arne,Koell, Peter
, p. 29 - 32 (1997)
Chiral N-acylated oxazolidin-2-ones readily available from D-xylose have been demonstrated to undergo highly diastereoselective acylation reactions via their lithium imide enolates to afford β-keto imides. These are easily purified and exhibit surprisingl
D-xylose derived oxazolidin-2-ones as chiral auxiliaries in stereoselective aldol reactions
Luetzen, Arne,Koell, Peter
, p. 1193 - 1206 (2007/10/03)
Chiral N-acylated oxazolidin-2-one derivatives from D-xylose have been shown to undergo diastereoselective aldol reactions via their lithium imide enolates to afford β-hydroxylated products. Aliphatic substrates and aldehydes were shown to yield 'non-Evan
D-xylose derived oxazolidin-2-ones as chiral auxiliaries in stereoselective alkylations
Koell, Peter,Luetzen, Arne
, p. 637 - 640 (2007/10/03)
Chiral N-acylated oxazolidin-2-ones readily available from D-xylose have been demonstrated to undergo highly diastereoselective alkylation reactions via their lithium imide enolates to afford α-branched products. These are easily purified and hydrolyzed w
