176978-29-3Relevant academic research and scientific papers
cis-4,6-dimethyl -2-phenyl-1,3-diselenane
Baudoux, Guy,Norberg, Bernadette,Wouters, Johan,Defrere, Laurent,Krief, Alain,Evrard, Guy
, p. 1505 - 1507 (1998)
In the crystal of the title compound, C12H16Se2, the packing involves quadrupolar interactions, and the 1,3-diselenane cycle adopts a chair conformation. This compound was synthesized using diselenocyanate and benzaldehyde.
Reaction of 1,3-diselenanes with metal amides
Krief, Alain,Defrere, Laurent
, p. 2667 - 2670 (2007/10/03)
1,3-Diselenanes are efficiently metallated by LDA or better by KDA. On conformationally rigid derivatives, metallation is more efficient on equatorial hydrogen and leads to 2-metallo-diselenanes bearing the metal in equatorial position.
