177327-03-6

Basic information

• Product Name: 1,4-Naphthalenedione, 6-(4-methyl-3-pentenyl)-
• CAS NO: 177327-03-6
• Molecular Formula: C16H16O2
• Molecular Weight: 240.302
• Mol File: 177327-03-6.mol

Chemical Properties

• CAS DataBase Reference: 1,4-Naphthalenedione, 6-(4-methyl-3-pentenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4-Naphthalenedione, 6-(4-methyl-3-pentenyl)-(177327-03-6)
• EPA Substance Registry System: 1,4-Naphthalenedione, 6-(4-methyl-3-pentenyl)-(177327-03-6)

Safety Data

• Hazardous Substances Data: 177327-03-6(Hazardous Substances Data)

Downstream Products

• 1456706-39-0 3-chloro-2-(3,4-dimethoxyanilino)-5,5-dimethyl-5,6,7,8-tetrahydroanthracene-1,4-dione 
• 1456706-40-3 3-chloro-2-(3,4-dimethoxyanilino)-8,8-dimethyl-5,6,7,8-tetrahydroanthracene-1,4-dione 
• 1456706-37-8 3-chloro-2-(4-methoxyanilino)-5,5-dimethyl-5,6,7,8-tetrahydroanthracene-1,4-dione 
• 1456706-38-9 3-chloro-2-(4-methoxyanilino)-8,8-dimethyl-5,6,7,8-tetrahydroanthracene-1,4-dione 
• 1456706-35-6 3-chloro-2-(3,4-dimethylanilino)-5,5-dimethyl-5,6,7,8-tetrahydroanthracene-1,4-dione 
• 1456706-36-7 3-chloro-2-(3,4-dimethylanilino)-8,8-dimethyl-5,6,7,8-tetrahydroanthracene-1,4-dione 
• 1456706-29-8 2-(4-acetoxyanilino)-5,5-dimethyl-5,6,7,8-tetrahydroanthracene-1,4-dione 
• 1456706-30-1 2-(4-acetoxyanilino)-8,8-dimethyl-5,6,7,8-tetrahydroanthracene-1,4-dione 
• 1456706-27-6 2-(4-methoxyanilino)-5,5-dimethyl-5,6,7,8-tetrahydroanthracene-1,4-dione 
• 1456706-28-7 2-(4-methoxyanilino)-8,8-dimethyl-5,6,7,8-tetrahydroanthracene-1,4-dione 
• 1456706-21-0 3-chloro-2-(4-methoxyphenoxy)-6-(4-methylpentyl)-1,4-naphthoquinone 
• 1456706-22-1 3-chloro-2-(4-methoxyphenoxy)-7-(4-methylpentyl)-1,4-naphthoquinones 
• 1254329-70-8 7-(4-methylpent-3-enyl)-3,4-bis(phenylamino)-1-pyridin-2-ylbenzo[g]isoquinoline-5,10-dione 
• 1254329-71-9 8-(4-methylpent-3-enyl)-3,4-bis(phenylamino)-1-pyridin-2-ylbenzo[g]isoquinoline-5,10-dione 

Relevant articles and documents

Bio-inspired dimerisation of prenylated quinones directed towards the synthesis of the meroterpenoid natural products, the scabellones

Stirring 2-geranyl-6-methoxy-1,4-hydroquinone in pyridine/O2 or 2-geranyl-6-methoxy-1,4-benzoquinone in pyridine/N2 affords the dimeric meroterpenoid natural products, scabellones A-C in modest to low yields and also identifies 2-methoxy-6-(4-methylpent-3-en-1-yl)-1,4-naphthoquinone (scabellone E) as a new natural product. The corresponding reaction of the des-methoxy analogue, 2-geranyl-1,4-benzoquinone in degassed pyridine for three days afforded the natural product cordiachromene A (15% yield) and 6-(4-methylpent-3-en-1-yl)-1,4-naphthoquinone (12%), the latter being a likely biosynthetic precursor to the marine meroterpenoid alkaloids, conicaquinones A and B.