177540-06-6Relevant articles and documents
Easy synthesis of 7-alkylbicyclo[3.3.1]non-6-en-3-ones by silica gelpromoted fragmentation of 3-alkyl-2-oxaadamant-1-yl mesylates
Camps, Pelayo,El Achab, Rachid,Font-Bardia, Merce,Goerbig, Diana,Morral, Jordi,Munoz-Torrero, Diego,Solans, Xavier,Simon, Montserrat
, p. 5867 - 5880 (1996)
A synthesis of 7-alkylbicyclo[3.3.1]non-6-en-3-ones 4b-f and 4j,k by reaction of the corresponding 3-alkyl-2-oxaadamant-1-yl mesylates 3 with silica gel in methylene chloride at room temperature, is described. The method failed to give enones 4a,g and the