177573-91-0

Upstream product

• 129423-29-6 [(1E)-3-phenylprop-1-en-1-yl]boronic acid 
• 126-30-7 2,2-Dimethyl-1,3-propanediol 
• 947-91-1 Diphenylacetaldehyde 
• 122-78-1 phenylacetaldehyde 
• 177573-86-3 (E)-4,4,5,5-tetramethyl-2-(3-phenylprop-1-en-1-yl)-1,3,2-dioxaborolane 
• 201733-56-4 2-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)-5,5-dimethyl-1,3,2-dioxaborinane 

Downstream Products

• 60341-39-1 (E)-4-phenylbut-2-enoic acid 

Relevant academic research and scientific papers

Transborylation of alkenylboranes with diboranes

Exchange of boryl moieties between alkenylboranes and diboron reagents has been postulated as a stereospecific cross-metathesis pathway with concomitant formation of mixed diboron reagents. DFT calculations propose a mechanism for the stereocontrolled C(sp2)-B/B′-B′ cross-metathesis with both symmetric and non-symmetric diboron reagents. This journal is

Nickel-catalysed carboxylation of organoboronates

A nickel/N-heterocyclic carbene (NHC) catalysed carboxylation of aryl-, heteroaryl- and alkenylboronates, affording the corresponding carboxylic acids, has been developed. This transformation proceeds under one atmosphere of CO 2 with a broad range of substrates and exhibits good functional group compatibility. the Partner Organisations 2014.