177573-91-0Relevant articles and documents
Transborylation of alkenylboranes with diboranes
Bru, Gerard,Carbó, Jorge J.,Dominguez-Molano, Paula,Fernández, Elena,Maza, Ricardo J.,Salvado, Oriol
, p. 13361 - 13364 (2021/12/17)
Exchange of boryl moieties between alkenylboranes and diboron reagents has been postulated as a stereospecific cross-metathesis pathway with concomitant formation of mixed diboron reagents. DFT calculations propose a mechanism for the stereocontrolled C(sp2)-B/B′-B′ cross-metathesis with both symmetric and non-symmetric diboron reagents. This journal is