1776-66-5Relevant articles and documents
Contributions to the Chemistry of Boron, 165 Diisopropyl- and Di-tert-butylborane Derivatives
Hoebel, Ulrike,Noeth, Heinrich,Prigge, Helene
, p. 325 - 337 (2007/10/02)
Methods for the preparation of diisopropyl- and di-tert-butylboranes R2BX (X = F, Cl, Br, I, OR', SCH3, NH2, NHR', and NR'2) are described.They use the readily accessible (dimethylamino)diorganylboranes 2a, b which are conveniently obtained from the (dimethylamino)dioxaborolane 1a by reaction with (CH3)2CHMgBr and (CH3)3CLi, respectively.The influence of the bulky groups R on the reactivity of these boranes is demonstrated for a number of examples.
Monoalkylborane aus Alkyliden(triphenyl)phosphoranen und Boran; Kombination von Ylidreaktionen und Hydroborierung
Bestmann, Hans Juergen,Suehs, Kurt,Roeder, Thomas
, p. 1098 - 1100 (2007/10/02)
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