177615-91-7Relevant academic research and scientific papers
Chloropalladation of propargyl thioethers: A facile synthesis of cyclopalladated compounds
Dupont, Jairton,Basso, Nara R.,Meneghetti, Mario R.
, p. 2299 - 2302 (1996)
The reaction of the propargyl thioethers Ph - C≡C - CH(R1)SR (R = Me, Pri, Ph and R1 = H, Me) with Li2PdCl4 in methanol at room temperature produced in very good yields (70-90%) five-membered palladocycles [Pd(C(Ph)=C(Cl)CH(R1)SR)(μCl)]2. Under the same reaction conditions the homopropargylthioether Ph - C≡C - (CH2)2SPh yielded unexpectedly the complex {Pd[S(Ph)(CH2)3C=O(Ph)](Cl)(μ-Cl)}2 resulting from the hydrolysis of the C≡C bond.
