17767-81-6Relevant articles and documents
PhI(OAc)2-mediated trifluoromethylthiolation/oxidative cyclization of ynamides
He, Guangke,Li, Yuan,Su, Shixuan,Wang, Jingyang,Yan, Zhipeng,Ye, Xingyuan
, p. 8746 - 8753 (2021/10/22)
A PhI(OAc)2-mediated trifluoromethylthiolation/oxidative cyclization of ynamides with the Shen reagent has been established herein, providing a facile access to CF3S-substituted oxazolidine-2,4-diones bearing a quaternary carbon center in 38-85% yields with chemoselectivities of up to 99/1.
Method for directly synthesizing oxazolidine -2 and 4 - diketone heterocyclic compound from alkyne amide (by machine translation)
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Paragraph 0017-0018, (2020/11/26)
The invention discloses a novel method for directly synthesizing oxazolidine -2 and 4 - diketone heterocyclic compounds from alkyne amide raw materials. The method has high catalytic reaction activity at 10% DEG C, N - methylpyrrolidone, dimethyl sulfoxide or N, N - dimethylformamide as a solvent, and is high in yield, wide in substrate application range and capable of synthesizing -2 oxazolidine 50 - 150 °C 4 - and 0.5 - 24h diketone heterocyclic compounds in a gram-scale manner; furthermore, the method has the advantages of low sensitivity -2 89 - 92%. to air, high chemical selectivity, easy separation and short reaction time of the product, and 4 - the like in the first time, and the method has the advantages of high yield.2 4. (by machine translation)