177723-39-6

Basic information

• Product Name: ethyl 6-O-tosyl-2,3-dideoxy-α-D-erythro-pyranoside
• Synonyms: ethyl 6-O-tosyl-2,3-dideoxy-α-D-erythro-pyranoside
• CAS NO: 177723-39-6
• Molecular Weight: 330.402
• Mol File: 177723-39-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: ethyl 6-O-tosyl-2,3-dideoxy-α-D-erythro-pyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 6-O-tosyl-2,3-dideoxy-α-D-erythro-pyranoside(177723-39-6)
• EPA Substance Registry System: ethyl 6-O-tosyl-2,3-dideoxy-α-D-erythro-pyranoside(177723-39-6)

Safety Data

• Hazardous Substances Data: 177723-39-6(Hazardous Substances Data)

Upstream product

• 98-59-9 p-toluenesulfonyl chloride 
• 23339-16-4 (2R,3S,6S)-6-ethoxy-2-(hydroxymethyl)tetrahydro-2H-pyran-3-ol 
• 2873-29-2 D-glucal triacetate 
• 3323-72-6 ethyl 4,6-di-O-acetyl-2,3-dideoxy-α-D-erythrohex-2-enopyranoside 
• 55735-69-8 ethyl 4,6-di-O-acetyl-2,3-dideoxy-α-D-erythrohexopyranoside 

Downstream Products

• 135103-85-4 N-Boc-O-Benzyl-(4S,5S)-5-amino-4-hydroxy-6-phenylhexanoic acid 
• 135103-80-9 N-Boc-O-benzyl-(4S,5S)-5-amino-4-hydroxy-6-phenylhexanoic acid methyl ester 
• 177723-43-2 6-azido-2,3,6-trideoxy-5-acetoxy-4-O-(phenylmethyl)-D-erythro-hexose-(propane-1,3-diyl)dithioacetal 
• 135103-84-3 methyl(4S)4-benzyloxy-4-<(2S)-N-Boc-aziridin-2-yl>-butanoate 
• 177723-45-4 methyl (4S,5R)-5-acetoxy-6-azido-4-(phenylmethoxy) hexanoate 
• 135103-82-1 6-azido-2,3,6-trideoxy-4-O-(phenylmethyl)-D-erythro-hexose-(propane-1,3-diyl)dithioacetal 
• 135103-81-0 ethyl 6-azido-2,3,6-trideoxy-4-O-(phenylmethyl)-α-D-erythro-hexopyranoside 
• 177723-44-3 (4S,5R)-5-acetoxy-6-azido-4-(phenylmethoxy) hexanal 
• 135103-83-2 methyl (4S,5R)-6-azido-5-hydroxy-4-(phenylmethoxy) hexanoate 
• 452084-66-1 tert-butyl (3S,4R)-4-(benzyloxy)-3-hydroxyazepane-1-carboxylate 
• 1054623-84-5 (3R,4R)-4-[4-(2-Benzyloxy-6-benzyloxycarbonyl-benzoyl)-3,5-bis-methoxymethoxy-benzoyloxy]-3-[4-(tert-butyl-dimethyl-silanyloxy)-benzoylamino]-azepane-1-carboxylic acid tert-butyl ester 
• 452084-61-6 tert-butyl (3R,4R)-3-azido-4-(benzyloxy)azepane-1-carboxylate 

Relevant articles and documents

STEREOSELECTIVE SYNTHESIS OF N-BOC-O-BENZYL-(4S,5S)-5-AMINO-4-HYDROXY-6-PHENYLHEXANOIC ACID, THE HYDROXYETHYLENE ISOSTERIC MOIETY OF POTENT HIV-1 PROTEASE INHIBITOR

N-Boc-O-benzyl-(4S,5S)-5-amino-4-hydroxy-6-phenylhexanoic acid is synthesized in a highly stereoselective way involving, as a key step, regioselective opening of carbohydrate-based aziridine ring.

Total synthesis of enantiomerically pure (-)-Balanol

The total synthesis of enantiomerically pure (-)-Balanol (1), using tri-O-acetyl-D-glucal as a chiral template for the central azepane fragment is described.