177798-90-2

Upstream product

• 177798-88-8 1-(4-Methoxy-benzyloxy)-3-((S)-toluene-4-sulfinyl)-propan-2-one 
• 51759-07-0 (4-methoxybenzyloxy)acetic acid methyl ester 
• 105-13-5 4-Methoxybenzyl alcohol 
• 88920-24-5 p-methoxybenzyloxy acetic acid 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 177798-89-9 (R)-1-(4-Methoxy-benzyloxy)-3-((S)-toluene-4-sulfinyl)-propan-2-ol 

Downstream Products

• 177798-96-8 4-(tert-Butyl-diphenyl-silanyloxy)-benzoic acid (S)-2-(tert-butyl-diphenyl-silanyloxy)-3-[((4E,6E,8E)-dodeca-4,6,8-trienyl)oxy]-propyl ester 
• 177798-94-6 tert-Butyl-[(S)-1-[((4E,6E,8E)-dodeca-4,6,8-trienyl)oxymethyl]-2-(4-methoxy-benzyloxy)-ethoxy]-diphenyl-silane 
• 177798-95-7 (R)-2-(tert-Butyl-diphenyl-silanyloxy)-3-[((4E,6E,8E)-dodeca-4,6,8-trienyl)oxy]-propan-1-ol 
• 177798-87-7 (S)-2-(tert-Butyl-diphenyl-silanyloxy)-3-(4-methoxy-benzyloxy)-propan-1-ol 

Relevant academic research and scientific papers

Enantioselective synthesis of (+)-isobretonin A

An enantioselective synthesis of (±)-isobretonin A is described. The chiral glycerol moiety was enantioselectively prepared by reduction of an optically active β-keto sulfoxide. The all-trans trienic part of the molecule was stereoselectively synthesized via reductive elimination of a 1,6-dibenzoate 2,4-diene with sodium amalgam.