177840-47-0

Basic information

• Product Name: bis(1-methyl-4,5-diphenylimidazol-2-yl)carbinol
• Synonyms: bis(1-methyl-4,5-diphenylimidazol-2-yl)carbinol
• CAS NO: 177840-47-0
• Molecular Weight: 496.612
• Mol File: 177840-47-0.mol

Chemical Properties

• CAS DataBase Reference: bis(1-methyl-4,5-diphenylimidazol-2-yl)carbinol(CAS DataBase Reference)
• NIST Chemistry Reference: bis(1-methyl-4,5-diphenylimidazol-2-yl)carbinol(177840-47-0)
• EPA Substance Registry System: bis(1-methyl-4,5-diphenylimidazol-2-yl)carbinol(177840-47-0)

Safety Data

• Hazardous Substances Data: 177840-47-0(Hazardous Substances Data)

Upstream product

• 668-94-0 4,5-diphenyl-1H-imidazole 
• 179679-67-5 bis(1-methyl-4,5-diphenyl-imidazol-2-yl)methanone 
• 50609-88-6 4,5-diphenyl-1-methyl-1H-imidazole 
• 119-53-9 2-hydroxy-2-phenylacetophenone 
• 109-94-4 formic acid ethyl ester 

Downstream Products

• 765277-64-3 Cu(I)[(6-aminopyrid-2-yl)methyl]bis(pyrid-2-ylmethyl)amine PF₆ 
• 402507-32-8 [Cu(tris(2-benzylaminoethyl)amine)(CH₃CN)]PF₆ 
• 175442-42-9 [(tris(3-Ph-pyrazolyl)methane)Cu(acetonitrile)](PF₆) 
• 175442-48-5 [(tris(3-Ph-pyrazolyl)methane)Cu(carbonyl)](PF₆) 
• 208852-13-5 [Cu(bis(1-methyl-4,5-diphenylimidaz-2-oyl)carbinol)2][CuBr₄] * H₂O 

Relevant articles and documents

Synthesis and structure of a 2 CuII 2 CuI constellation ligated by the new biimidazole, bis(1-methyl-4,5-diphenylimidaz-2-oyl)carbinol

The new biimidazole, bis(1-methyl-4,5-diphenylimidaz-2-oyl)carbinol, BimOH, is synthesized and employed to form the novel tetrameric constellation [Cu4(BimOH)2(BimO)2]4+, involving an (Nim)2CuII(OR)2Cu II(Nim)2 centre with a CuII...CuII separation of 2.998(4) A and two CuI(Nim)2 moieties ca. 5 A from the Cu2 centre, each with an N-Cu-N angle of 169.3(4)°.

Formation of exceptionally weak C-C bonds by metal-templated pinacol coupling

The ability of the bis(imidazolyl)ketone ligand BMdiPhIK (bis(1-methyl-4,5-diphenylimidazolyl)ketone) to function as a redox active ligand has been investigated. The reduction of [M(BMdiPhIK)Cl2] (M = Fe and Zn) complexes