177956-76-2

Basic information

• Product Name: Methyl (Z)-2-(phenylselanylcarbonylethyl)cyclohexylideneacetate
• CAS NO: 177956-76-2
• Molecular Weight: 365.331
• Mol File: 177956-76-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Methyl (Z)-2-(phenylselanylcarbonylethyl)cyclohexylideneacetate(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl (Z)-2-(phenylselanylcarbonylethyl)cyclohexylideneacetate(177956-76-2)
• EPA Substance Registry System: Methyl (Z)-2-(phenylselanylcarbonylethyl)cyclohexylideneacetate(177956-76-2)

Safety Data

• Hazardous Substances Data: 177956-76-2(Hazardous Substances Data)

Upstream product

• 1655-07-8 ethyl 2-oxocyclohexane carboxylate 
• 2275-26-5 3-(2-oxocyclohexyl)propionic acid 
• 854709-49-2 1-(2-Carboxy-ethyl)-2-oxo-cyclohexanecarboxylic acid 
• 1666-13-3 diphenyl diselenide 
• 23974-72-3 sodium phenylselenide 
• 177956-75-1 Methyl (Z)-2-(carboxyethyl)cyclohexylideneacetate 
• 93865-05-5 3-(1-ethoxycarbonyl-2-oxo-cyclohexyl)-propionic acid ethyl ester 

Relevant articles and documents

Stereoselective Synthesis of (cis-Hydrindane) Models for C-18 Radical Reactivity in Steroid C/D Rings

The keto-acid 5 undergoes stereospecific Peterson reaction to afford the (Z)-α-unsaturated ester-acid 6, and the derived phenyl selenoester cyclises also stereospecifically to the cis-hydrindanone 8 via a 5-exo acyl radical process; the ketone 8 is transformed through enone 11 into the diene-acids 2 and 3, models for study of C-18 radical reactions in steroid C/D systems.