177965-26-3Relevant academic research and scientific papers
Manganese(III) acetate catalyzed oxidative amination of benzylic C(sp3)-H bonds with nitriles
Zhang, Yaxing,Dong, Jianyu,Liu, Lixin,Liu, Long,Zhou, Yongbo,Yin, Shuang-Feng
supporting information, p. 2897 - 2901 (2017/04/11)
Mn-Catalyzed oxidative amination of benzylic C(sp3)-H bonds with nitriles is disclosed, which enables the synthesis of a broad range of secondary amides in moderate to excellent yields under mild conditions. The interaction between Mn(iii) and DDQ facilitates the oxidation and makes it highly efficient and selective.
Peroxidation of C-H bonds adjacent to an amide nitrogen atom under mild conditions
Yu, Hui,Shen, Jie
supporting information, p. 3204 - 3207 (2014/07/08)
Under mild conditions, the oxidative functionalization of C-H bonds adjacent to an amide nitrogen atom was achieved. tert-Butylperoxyamido acetal was obtained in high yields and could be further converted into α-substituted amides by treatment with Grigna
HClO4-SiO2 as an efficient and recyclable catalyst for the synthesis of amide derivatives
Song, Weibin,Ma, Lei,Hu, Lihong
experimental part, p. 3186 - 3196 (2011/09/20)
An efficient and clean procedure for amide alkylation is reported by direct condensation of equimolar amounts of benzylic and allylic alcohols with primary amides in the presence of silica perchloric acid (HClO4-SiO 2). The direct co
