17797-03-4Relevant academic research and scientific papers
Intramolecular Chalcogenylation of Isooxazolines Mediated by PhICl 2and Diorganyl Disulfides or Diselenides
Zhang, Dongke,Zhang, Jingran,Li, Xiaoxian,Yu, Zhenyang,Li, Yadong,Sun, Fengxia,Du, Yunfei
, p. 411 - 420 (2021/10/05)
Reactive organosulfenyl chlorides (ArSCl) or selenenyl chlorides (ArSeCl), generated in situ from the reaction of PhICl 2with diorganyl disulfides or diselenides, enable the intramolecular oxidative cyclization/chalcogenylation of β,γ-unsaturated oximes, leading to the formation of a series of chalcogenylated isooxazolines in good to excellent yield.
Trichloroisocyanuric acid-promoted thiolation of phosphites by thiols
Chen, Yingying,Li, Meichao,Gong, Zhangshui,Shen, Zhenlu
, p. 19 - 27 (2020/08/06)
A simple and convenient method for the synthesis of thiophosphates by coupling of phosphites with thiols under mild conditions has been developed. The reactions were promoted by trichloroisocyanuric acid (TCCA) and were carried out at room temperature in
RECOVERY METHOD OF SYNTHETIC SOLVENT
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Paragraph 0037; 0038, (2018/10/16)
PROBLEM TO BE SOLVED: To provide a method for recovering a solvent industrially advantageously in order to reutilize the solvent, after synthesizing N-(cyclohexylthio)phthalimide in the solvent of a saturated hydrocarbon. SOLUTION: In a recovery method of
A metal free chlorothiolation strategy for synthesis of vinyl sulfides from internal alkynoates
Surineni, Naresh,Buragohain, Pori,Saikia, Bishwajit,Barua, Nabin C.,Baruah, Rajani K.
supporting information, p. 6965 - 6969 (2015/11/27)
A metal free chlorothiolation approach has been developed for conversion of internal alkynoates to vinyl sulfides and also utilized mild PIDA mediated oxidation to yield the corresponding sulfoxides.
Synthesis of aryl thioethers through the N -chlorosuccinimide-promoted cross-coupling reaction of thiols with Grignard reagents
Cheng, Jun-Hao,Ramesh, Chintakunta,Kao, Hsin-Lun,Wang, Yu-Jen,Chan, Chien-Ching,Lee, Chin-Fa
, p. 10369 - 10374 (2013/01/15)
A convenient one-pot approach for the synthesis of aryl sulfides through the coupling of thiols with Grignard reagents in the presence of N-chlorosuccinimide is described. The sulfenylchlorides were formed when thiols were treated with N-chlorosuccinimide, and the resulting sulfenylchlorides were then directly reacted with Grignard reagents to provide aryl sulfides in good to excellent yields under mild reaction conditions. Functional groups including ester, fluoro, and chloro are tolerated by the reaction conditions employed. It is important to note that this method has a short reaction time (30 min in total) and represents an alternative approach for the synthesis of aryl sulfides over the existing protocols.
A traceless, one-pot preparation of unsymmetric disulfides from symmetric disulfides through a repeated process involving sulfenic acid and thiosulfinate intermediates
Han, Minsoo,Lee, Jong Tak,Hahn, Hoh-Gyu
experimental part, p. 236 - 239 (2011/02/28)
A variable group of unsymmetric disulfides was prepared under mild reaction conditions and in high yields through the reaction of symmetric disulfides with sulfuryl chloride followed by treatment with thiols in the presence of water.
Electron Spin Resonance Study of N-alkyl-N-(alkylthio)aminyl Radicals
Miura, Yozo,Asada, Hidetsugu,Kinoshita, Masayoshi,Ohta, Katsuhisa
, p. 3450 - 3455 (2007/10/02)
A variety of N-alkyl-N-(alkylthio)aminyl radicals (2), R1N.SR2, were generated by hydrogen-atom abstraction from N-(alkylthio)alkylamines and were studied by electron spin resonance (ESR) spectroscopy.When both R1 and Rsu
