17797-03-4

Basic information

• Product Name: Cyclohexanesulfenyl chloride
• Synonyms: Cyclohexanesulfenyl chloride
• CAS NO: 17797-03-4
• Molecular Formula: C₆H₁₁ClS
• Molecular Weight: 150.6695
• Mol File: 17797-03-4.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 198.2°Cat760mmHg
• Flash Point: 77.4°C
• Appearance: /
• Density: 1.11g/cm³
• Vapor Pressure: 0.513mmHg at 25°C
• Refractive Index: 1.512
• CAS DataBase Reference: Cyclohexanesulfenyl chloride(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanesulfenyl chloride(17797-03-4)
• EPA Substance Registry System: Cyclohexanesulfenyl chloride(17797-03-4)

Safety Data

• Hazardous Substances Data: 17797-03-4(Hazardous Substances Data)

Usage

InChI:InChI=1/C6H11ClS/c7-8-6-4-2-1-3-5-6/h6H,1-5H2

Upstream product

• 2550-40-5 1,2-dicyclohexyl disulfide 
• 1569-69-3 Cyclohexanethiol 
• 110-82-7 cyclohexane 

Downstream Products

• 4251-13-2 thiocyanatocyclohexane 
• 93044-23-6 Cyclohexyl-<2-chlor-cyclohexyl>-sulfid 
• 735269-14-4 1-cyclohexyl-2-(4-methoxyphenyl)disulfane 
• 1264674-62-5 (cyclohexyldisulfanyl)-1H-1,2,4-triazole 
• 28084-58-4 2-(cyclohexyldisulfanyl)benzo[d]thiazole 
• 26437-23-0 thiophosphoric S-cyclohexyl ester O,O'-diethyl ester 
• 17796-82-6 N-(cyclohexylthio)-phthalimide 
• 61671-42-9 4-fluorophenyl cyclohexyl sulfide 
• 59693-93-5 (4-methylphenyl)cyclohexyl sulfane 
• 7570-92-5 cyclohexyl phenyl sulphide 
• 99315-17-0 S-cyclohexyl hexanethioate 

Relevant articles and documents

Intramolecular Chalcogenylation of Isooxazolines Mediated by PhICl 2and Diorganyl Disulfides or Diselenides

Reactive organosulfenyl chlorides (ArSCl) or selenenyl chlorides (ArSeCl), generated in situ from the reaction of PhICl 2with diorganyl disulfides or diselenides, enable the intramolecular oxidative cyclization/chalcogenylation of β,γ-unsaturated oximes, leading to the formation of a series of chalcogenylated isooxazolines in good to excellent yield.

RECOVERY METHOD OF SYNTHETIC SOLVENT

PROBLEM TO BE SOLVED: To provide a method for recovering a solvent industrially advantageously in order to reutilize the solvent, after synthesizing N-(cyclohexylthio)phthalimide in the solvent of a saturated hydrocarbon. SOLUTION: In a recovery method of

Synthesis of aryl thioethers through the N -chlorosuccinimide-promoted cross-coupling reaction of thiols with Grignard reagents

A convenient one-pot approach for the synthesis of aryl sulfides through the coupling of thiols with Grignard reagents in the presence of N-chlorosuccinimide is described. The sulfenylchlorides were formed when thiols were treated with N-chlorosuccinimide, and the resulting sulfenylchlorides were then directly reacted with Grignard reagents to provide aryl sulfides in good to excellent yields under mild reaction conditions. Functional groups including ester, fluoro, and chloro are tolerated by the reaction conditions employed. It is important to note that this method has a short reaction time (30 min in total) and represents an alternative approach for the synthesis of aryl sulfides over the existing protocols.