177977-65-0

Basic information

• Product Name: ((1R,2S)-2-Azido-1,2-diphenyl-ethoxy)-tert-butyl-dimethyl-silane
• Synonyms: ((1R,2S)-2-Azido-1,2-diphenyl-ethoxy)-tert-butyl-dimethyl-silane
• CAS NO: 177977-65-0
• Molecular Weight: 353.539
• Mol File: 177977-65-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ((1R,2S)-2-Azido-1,2-diphenyl-ethoxy)-tert-butyl-dimethyl-silane(CAS DataBase Reference)
• NIST Chemistry Reference: ((1R,2S)-2-Azido-1,2-diphenyl-ethoxy)-tert-butyl-dimethyl-silane(177977-65-0)
• EPA Substance Registry System: ((1R,2S)-2-Azido-1,2-diphenyl-ethoxy)-tert-butyl-dimethyl-silane(177977-65-0)

Safety Data

• Hazardous Substances Data: 177977-65-0(Hazardous Substances Data)

Upstream product

• 1439-07-2 (R,R)-trans-stilbene epoxide 
• 133522-22-2 (1R,2S)-2-azido-1,2-diphenylethan-1-ol 
• 18162-48-6 tert-butyldimethylsilyl chloride 

Downstream Products

• 178151-42-3 (1S,2R)-1,2-diphenyl-2-<(1,1-dimethylethyl)dimethylsiloxy>ethylamine 

Relevant articles and documents

Asymmetric catalysis via chiral aziridines

The chiral bis(aziridines) 4, 6 and 7 have been synthesized and evaluated as chelating ligands for a variety of asymmetric transformations mediated by metals. The processes studied were the asymmetric addition of osmium tetroxide to olefins, copper-catalyzed asymmetric cyclopropanation and aziridination, palladium-catalyzed asymmetric allylic alkylation and asymmetric 1,2-addition of organolithium reagents to imines. In the best cases an enantiomeric excess >95% was obtained. Acta Chemica Scandinavica 1996.