178042-98-3

Basic information

• Product Name: tert-butyl 4-methoxy-2-(p-tolylthio)phenylcarbamate
• Synonyms: tert-butyl 4-methoxy-2-(p-tolylthio)phenylcarbamate
• CAS NO: 178042-98-3
• Molecular Weight: 345.463
• Mol File: 178042-98-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: tert-butyl 4-methoxy-2-(p-tolylthio)phenylcarbamate(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl 4-methoxy-2-(p-tolylthio)phenylcarbamate(178042-98-3)
• EPA Substance Registry System: tert-butyl 4-methoxy-2-(p-tolylthio)phenylcarbamate(178042-98-3)

Safety Data

• Hazardous Substances Data: 178042-98-3(Hazardous Substances Data)

Upstream product

• 103-19-5 di(p-tolyl) disulfide 
• 18437-68-8 tert-butyl N-(4-methoxyphenyl)carbamate 
• 24424-99-5 di-tert-butyl dicarbonate 
• 104-94-9 4-methoxy-aniline 
• 106501-78-4 tert-butyl (4,4-dimethoxycyclohexa-2,5-dien-1-ylidene)carbamate 
• 106-45-6 para-thiocresol 

Downstream Products

• 178043-05-5 [4-Methoxy-2-(toluene-4-sulfinyl)-phenyl]-carbamic acid tert-butyl ester 

Relevant articles and documents

An Efficient Coupling of p-Quinone Mono-Imine Ketals and Aryl/Alkyl Thiols: Rapid Synthesis of Biaryl/Aryl–Alkyl Sulfides

We report a fast, efficient, and metal-free protocol for the synthesis of unsymmetrical biaryl sulfides and aryl–alkyl sulfides (4-methoxy-2-sulfanyl-phenylcarbamates) under catalytic influence of 2,4-dinitrobenzoic acid. The reaction proceeded in a regioselective anti-Michael addition fashion and all the products were obtained within a very short period of time and in good to excellent yields.